Chemical shifts in ESCA and NMR
โ Scribed by U. Gelius; G. Johansson; H. Siegbahn; C.J. Allan; D.A. Allison; J. Allison; K. Siegbahn
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 790 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0368-2048
No coin nor oath required. For personal study only.
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## Czkulations al ESCA chemical shifts, using Jolly's equivalent core approximation 2nd the MIND0/3 semi~1~pIk5 SCF hIC? method, hzve given resu!ts in resonable agreement with experiment.
29Si chemical shifts in a wide variety of silicates in crystalline, glassy and gel states have been related to a parameter, P, which takes into account the electronegativity and the structural description of the silicate units as well as the ionic potential of the modifier cation. The relation, G(pp