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Chemical shift measurements of chlorine K X-ray spectra using a high-resolution PIXE system

โœ Scribed by T. Tada; M. Hayashi; H. Fukuda; J. Hasegawa; Y. Oguri


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
195 KB
Volume
266
Category
Article
ISSN
0168-583X

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Chemical shift and lineshape of high-res
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NiB, NiSi 2 , acetylacetonate, K 2 Ni(CN) 4 , and some nickel complexes] were measured using a doublecrystal x-ray fluorescence spectrometer. The shift, asymmetry and spin-orbit splitting energy were extracted from the measured spectra. The asymmetric Ka lineshape was deconvoluted by Lorentzian func