Chemical shift changes on conversion of benzofurans to dihydrobenzofurans; the large effect on the proton ortho to the furan oxygen
β Scribed by Suraj B. Kalidhar
- Book ID
- 102528500
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 128 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0749-1581
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β¦ Synopsis
Abstract
A comparison of the ^1^H NMR spectra of benzofuran and its dihydrofuran shows that the benzene proton ortho to the furan oxygen undergoes a larger change in chemical shift than those for the other protons. This observation is useful for locating the fusion sites of the furan ring in naturally occurring benzofuran derivatives.
π SIMILAR VOLUMES
29Si nuclear magnetic resonance spectroscopy has shown that when dialkoxysilanes are milled with magnesium chloride, a component of the Ziegler-Natta catalyst, the 295i nucleus becomes more deshielded. Calculations on the change in 29Si NMR shielding when the Si-O bond distances and O-Si-O bond angl