Chemical shielding anisotropy of 13C and 15N in acetonitrile
โ Scribed by S. Kaplan; A. Pines; R.G. Griffin; J.S. Waugh
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 248 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
โฆ Synopsis
Hi& resolution 13C and l5 N NMR spectra fiave been obtained for powdered C&CN. The presence of resolved dip&r structure in the ' 3 C spectra permits the cancIusion that the symmetry axis of the * 3C shielding tensor lies
๐ SIMILAR VOLUMES
The 13C chemical shielding anisotropies of benzene, toluene, he~~e~yl~a~ne and acetone molecules are calculated theoretically by a linear combination of gauge invariant atomic orbitals -molecular orbital theory using the MIND0 method.
The principal elements of the axially symmetric nitrile ~3C chemical shift tensor, and the C-=N bond distance of solid CH3CN have been determined from both static and sample spinning NMR experiments at 78 and 140 K. The spectra show no significant differences between the a and /3 forms of the solid