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Chemical selectivities disguised by mass diffusion. III. A comparison of two versions of a simple model of mixing-disguised reactions in solution. 3rd communication on the selectivity of chemical processes

✍ Scribed by Felix Nabholz; Roland J. Ott; Paul Rys

Publisher
John Wiley and Sons
Year
1977
Tongue
German
Weight
503 KB
Volume
60
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

A simple mixing‐reaction model has been developed [1] which allows a description and simulation of the coupling of the mass diffusion with the chemical reaction during the mixing process of two miscible reactant solutions. For competitive, consecutive as well as for competitive, parallel second‐order reactions the general behaviour and the dependence of the product distribution on diffusion effects are calculated for semi‐continuous reaction conditions using various simplifying assumptions. The usefulness of these assumptions is discussed with reference to the calculated predictions of two versions of the mixing‐reaction model.

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