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Chemical Reactivity of Singlet Sigma Oxygen (b 1 Σ g+ ) in Solution

✍ Scribed by Scurlock, Rodger D.; Wang, Bojie; Ogilby, Peter R.


Book ID
120412922
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
188 KB
Volume
118
Category
Article
ISSN
0002-7863

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Mechanism of singlet oxygen interaction
✍ Alexander P. Darmanyan 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 564 KB

The values of relative 0s ('A,) luminescence rate constant (kp ) in thirty-two solvents with ionization potentials IP = 8-l 1 eV are satisfactorily described by a linear dependence of log (kp /n 2, versus IP with a slope of -0.30 eV-i. Singlet oxygen acting as an electron acceptor forms a loose exci