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Chemical reactivity of analogous technetium(V) and rhenium(V) dioxo complexes

✍ Scribed by C. Kremer; A. León; E. Kremer

Book ID
112706367
Publisher
Springer
Year
1993
Tongue
English
Weight
339 KB
Volume
176
Category
Article
ISSN
1588-2780

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Multinuclear NMR Studies of Ligand-Exchange Reactions on Analogous Technetium(V) and Rhenium(V) Complexes. Relevance to nuclear medicine
✍ Lothar Helm; Karen Deutsch; Edward A. Deutsch; André E. Merbach 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 German ⚖ 468 KB

The kinetics of pyridine exchange on truns-[MO,(py),]' have been followed by 'H-NMR in CD,NO, for M = Re, Tc: k298/s-' = (5.5 i 0.1) x 0.04 i 0.02; A H #/kJmol-' = 11 1 f-3, 101 f 9; dSf/JK-'mol-' = +28 \* 10, +68 \* 35. For the ReV complex, pyridine and oxygen exchanges have been measured simultane