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Chemical Reactivity Controlled by Negative Hyperconjugation: A Theoretical Study

โœ Scribed by Sten O. Nilsson Lill; Guntram Rauhut; Ernst Anders


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
230 KB
Volume
9
Category
Article
ISSN
0947-6539

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By a wavepacket propagation, we demonstrate the possibility of controlling the photodissociation branching ratio between two fragment channels by a single ultrashort linearly chirped laser pulse. It is found that a negatively chirped pulse of a moderate chirp rate completely prohibits the production