Phospholes ,synthesised by an improved procedure, undergo Dials-Alder reactions at high pressure but not dipolar cycloadditions to nitrile oxides (which deoxygenate) or diaxomethanes ( which can, however, trap the phosphole oxides) . Diphenylketene gives an unexpected spirophosphorane with phosphole
Chemical Reactions and Other Behaviors of High Energetic Materials under Static Ultrahigh Pressures
โ Scribed by Goto, Naoyuki; Yamawaki, Hiroshi; Tonokura, Kenichi; Wakabayashi, Kunihiko; Yoshida, Masatake; Koshi, Mitsuo
- Book ID
- 120810328
- Publisher
- Trans Tech Publications, Ltd.
- Year
- 2004
- Tongue
- English
- Weight
- 402 KB
- Volume
- 465-466
- Category
- Article
- ISSN
- 1662-9752
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Developing and testing novel energetic materials is an expanding branch of the materials sciences. Reaction, detonation or explosion of such materials invariably produce extremely high pressures and temperatures. To study the equations-of-state (EOS) of energetic materials in extreme regimes both sh
Infrared spectra of the cubic and the monoclinic phases of tetracyanoethylene have been investigated as a function of pressure at room temperature. The cubic phase, a low-temperature phase stable below 318 K at ambient pressure, appeared to be stable up to 6 GPa. The high-temperature monoclinic form