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Chemical properties, magnetic and e.p.r. studies of pyrazole copper(II) complexes

✍ Scribed by Janina Goslar; Paweł B. Sczaniecki; Marian M. Strawiak; Jerzy Mroziński

Publisher
Springer
Year
1988
Tongue
English
Weight
522 KB
Volume
13
Category
Article
ISSN
0340-4285

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## Abstract A new binucleating bis(terdentate) ligand, 3,5‐[3‐bis(2‐pyridyl)pyrazole‐1‐ylmethyl]pyrazole (HL^2^), was synthesized. Reaction of the deprotonated ligand L^2^ with hydrated Cu^II^ salts gives (μ‐pyrazolato)(μ‐hydroxido)‐bridged binuclear and tetranuclear complexes [L^2^Cu~2~(μ‐OH)(ClO~