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Chemical processes during forming of polynosic fibre in the presence of formaldehyde

✍ Scribed by A. Kh. Khakimova; N. B. Sokolova; N. S. Nikolaeva


Publisher
Springer US
Year
1971
Tongue
English
Weight
171 KB
Volume
1
Category
Article
ISSN
0015-0541

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Mechanism of the chain process forming H
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A mechanism for the formation in a chain of H,, CO, and HCOOH in the photooxidation of formaldehyde is proposed. This mechanism is initiated by the addition of HO, to formaldehyde. Hydrogen atoms are produced by the thermal dissociation of the HOCH,O radical: HOCH,O -+ H + HCOOH; AH = + 3.2 kcal/mol