Chemical Preparation, Structural Investigation, and Thermal Behavior of a New Cyclohexaphosphate: Zn2Cs2P6O18 · 8H2O
✍ Scribed by S. Abid; M. Rzaigui; M.T. Averbuch-Pouchot
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 270 KB
- Volume
- 110
- Category
- Article
- ISSN
- 0022-4596
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The cyclohexaphosphoric acid is added until pH 2 is Three new cyclohexaphosphates with the general formula reached in the final solution. After some days of slow Ca 2 M 2 P 6 O 18 ؒ 6H 2 O (M ؍ K, Tl, Rb) are reported. They crystal-evaporation at room temperature, crystals appeared with lize with
Preparation and complete struitural characterization by \(\mathrm{X}\)-ray diffraction, IR absorption. DTA, and GTA are given for a new lithium cyclohexaphosphate hydrate: \(\mathrm{Li}_{6} \mathrm{P}_{6} \mathrm{O}_{18} \cdot 9 \mathrm{H}_{2} \mathrm{O}\). This compound is monoclinic, \(\mathrm{C}
## Abstract Two 2D Anderson polyoxomolybdate‐based compounds, [{Ni(H~2~O)~4~}~2~{Ni(OH)~6~Mo~6~O~18~}]·4H~2~O (1) and [Ni(H~2~O)~6~][Ag~2~{Ni(OH)~6~Mo~6~O~18~}]·8H~2~O (2), were synthesized and characterized by elemental analysis, IR spectroscopy, SEM, and single‐crystal XRD. Their thermal behavior