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Chemical ionization mass spectrometry of some aromatic and aliphatic oximes

✍ Scribed by André Maquestiau; Yves Van Haverbeke; Robert Flammang; Philippe Meyrant

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
270 KB
Volume
15
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Aromatic and aliphatic oximes are protonated under methane or isobutane chemical ionization conditions. The structural identity of the [MHH~2~O]^+^˙ ions with nitrilium cations is established by the mass analysed ion kinetic energy method after collisional activation. The results also show the stereospecific nature of the transposition in the gas phase.

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