Selective proton transfer of unsaturated
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Yoshihiko Ikeda; Junzo Ukai; Nobuo Ikeda; Hisashi Yamamoto
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Article
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1987
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Elsevier Science
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French
β 961 KB
Deconjugative protonation of dienolates from (E)-2alkenoate using potassium disilazide as the base gives (z)-3alkenoate predominantly. A trail-following pheromone for subterranean termites is synthesized stereoselectively with this method. Deconjugative protonation of trienolates from (E,E)-2,4\_t