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Chemical Effects of (n,2n) Activation of Iodine in the Alkyl Iodides 1,2

โœ Scribed by McCauley, Charles E.; Hilsdorf, George J.; Geissler, Paul R.; Schuler, Robert H.

Book ID
126062080
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
903 KB
Volume
78
Category
Article
ISSN
0002-7863

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Photolysis of alkyl iodides at 147.0 nm.
Photolysis of alkyl iodides at 147.0 nm. The reaction H + CnH2n + 1I โ†’ HI + CnH2n + 1
โœ R. E. Rebbert; S. G. Lias; P. Ausloos ๐Ÿ“‚ Article ๐Ÿ“… 1973 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 697 KB

The 147 nm (8.4 eV) photolysis of gaseous C2H51, n-C3H71, and sec-C3H71 was investigated in the presence of and absence of HI. The main overall processes are: These dissociative processes occur mainly as a result of initial cleavage of the weak C-1 bond, followed by decomposition of the internally