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Chemical detection of carbon-metal bonds: From distinct sigma-bonding of main-group metals to ambiguous pi-bonding with transition metals

✍ Scribed by John J. Eisch


Book ID
108138353
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
1020 KB
Volume
364
Category
Article
ISSN
0020-1693

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The mass spectra of several compounds with bonds between transition metals and main group IV elements are discussed. Ionization potentials (1) and appearance potentials of [M'X31+ ions (A) were measured and bond dissociation energies D(M-M') calculated. Values of D(Mo-Sn) from (1)-CgHJ2Mo-(L)SnMe, w