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Chemical derivatization of endohedral metallofullerene La@C82 with digermirane

โœ Scribed by Takeshi Akasaka; Tatsuhisa Kato; Shigeru Nagase; Kaoru Kobayashi; Kazunori Yamamoto; Hideyuki Funasaka; Takeshi Takahashi

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
293 KB
Volume
52
Category
Article
ISSN
0040-4020

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Endohedral metallofullerenes Ce@C 82 , Ce 2 @C 80 , Nd@C 82 and Nd 2 @C 80 undergo gas phase ion/molecule reactions with the ion system from self-chemical ionization of vinyl acetate, and exohedral derivatives are thus generated. A new heterocycle is formed from metallofullerenes and a C 2 H 3 O + c

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La@C 82 is recognized by an isophthaloyl-bridged porphyrin dimer forming a stable 1:1 supramolecular complex with an association constant K assoc = (67.3 ยฑ 3.2) ร‚ 10 3 M ร€1 .