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Chemical Basis of DNA Sugar−Phosphate Cleavage by Low-Energy Electrons

✍ Scribed by Zheng, Yi; Cloutier, Pierre; Hunting, Darel J.; Sanche, Léon; Wagner, J. Richard

Book ID
120423416
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
167 KB
Volume
127
Category
Article
ISSN
0002-7863

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## Abstract The results of a CNDO/2 all‐valence electron crystal orbital study are reported for the sugar‐phosphate chain of DNA. The valence and conduction bandwidths are found to be large enough to make electronic delocalization through this backbone possible. Different mechanisms for charge carr