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Chemical and phase composition of manganese oxides obtained by Mn(II) oxidation in nitrate solutions

โœ Scribed by Ye.V. Kuz'minskii; A.A. Andriiko; L.I. Nyrkova


Book ID
108006253
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
395 KB
Volume
52
Category
Article
ISSN
0378-7753

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Manganese(II) is oxidized by ozone in acid solution, k ฯญ (1.5 ฯฎ 0.2) ฯซ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 ฯช1 ฯช1 3 ฯช 1 ฯช 1 10 M s k ฯญ (1.8 ฯฎ 0.2) ฯซ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ฯฉ 2ฯฉ Mn MnO , quently reacts rapidly with to for