Oxidation of manganese(II) by ozone and
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Frank Jacobsen; Jerzy Holcman; Knud Sehested
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Article
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1998
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John Wiley and Sons
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English
โ 182 KB
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Manganese(II) is oxidized by ozone in acid solution, k ฯญ (1.5 ฯฎ 0.2) ฯซ in HClO 4 and in H 2 SO 4 . The plausible mechanism is 3 ฯช1 ฯช1 3 ฯช 1 ฯช 1 10 M s k ฯญ (1.8 ฯฎ 0.2) ฯซ 10 M s an oxygen atom transfer from O 3 to producing the manganyl ion which subse-2ฯฉ 2ฯฉ Mn MnO , quently reacts rapidly with to for