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Chemical and Genetic Study of Ligularia anoleuca and L. veitchiana in Yunnan and Sichuan Provinces of China

✍ Scribed by Hajime Nagano; Midori Kanda; Hiroka Yamada; Ryo Hanai; Xun Gong; Chiaki Kuroda


Publisher
John Wiley and Sons
Year
2010
Tongue
German
Weight
148 KB
Volume
93
Category
Article
ISSN
0018-019X

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✦ Synopsis


Chemical and genetic study of Ligularia anoleuca and L. veitchiana, which belong to section Ligularia, series Speciosae, was carried out. From L. anoleuca samples, collected in Yunnan and Sichuan Provinces of China, a new compound, furanoeremophil-1(10)-en-6a-ol, was isolated together with known 6b-{[2-(hydroxymethyl)prop-2-enoyl]oxy}furanoeremophil-1(10)-ene and 1b,10b-epoxy-6b-{[2-(hydroxymethyl)prop-2-enoyl]oxy}furanoeremophilane. From L. veitchiana samples, collected in Yunnan Province, euparin, 2-isopropenyl-5,6-dimethoxybenzofuran, and 6-hydroxy-3b-methoxytrementone were isolated. DNA Sequencing of the internal transcribed spacers of the ribosomal RNA gene showed that the two species are not particularly close despite morphological similarities, in agreement with the chemical results.


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## Abstract Root chemicals and evolutionarily neutral DNA regions in __L. cyathiceps__ samples collected in the Zhongdian (Shangrila) County of Yunnan, P.β€…R. China, were examined. Twenty compounds were isolated, including three new ones, 1__Ξ²__,10__Ξ²__‐epoxy‐6__Ξ²__‐(propionyloxy)furanoeremophilan‐9