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Chemical and electrochemical reduction of titanium(IV) aryloxides

โœ Scribed by Durfee, Loren D.; Latesky, Stanley L.; Rothwell, Ian P.; Huffman, John C.; Folting, Kirsten


Book ID
120190516
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
676 KB
Volume
24
Category
Article
ISSN
0020-1669

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The titanium-mediated cyclization of d,o-enones by using dichlorotitanium diphenoxide-cyclohexylmagnesium chloride diastereoselectively afforded cis-substituted cyclopentanols and was thus found to parallel the stoichiometric and catalytic titanocene-mediated reactions.