Reductive cyclization of enones by titan
โ
Long Guo Quan; Jin Kun Cha
๐
Article
๐
2001
๐
Elsevier Science
๐
French
โ 57 KB
The titanium-mediated cyclization of d,o-enones by using dichlorotitanium diphenoxide-cyclohexylmagnesium chloride diastereoselectively afforded cis-substituted cyclopentanols and was thus found to parallel the stoichiometric and catalytic titanocene-mediated reactions.