Chemical and electrochemical generation of nickel(III) poly-aza macrocyclic complexes in aqueous and non-aqueous solutions
β Scribed by Antonio Poggi; Luigi Fabbrizzi
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 118 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1693
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Polarization studies of silver Galvanostatic charging of electropolished silver electrodes was carried out at room temperature in 1.0 and 3.0 M aqueous KOH (not presaturated with Ag20; cf. ref. 1) at current densities of 0.25 mAcm-z. The results are summarized in Fig. for 3.0 M KOH but it is releva
A very convenient synthesis of an 18-membered triaza-macrocyclic ligand bearing one endocyclic terpyridine unit and three acetate pendant groups is reported. This nonadentate ligand forms very stable neutral lanthanide complexes in aqueous solution and efficiently shields the metal ion from the wate