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Chemical Analogues of the Catalytic Centers of Molybdenum and Tungsten Dithiolene-Containing Enzymes

✍ Scribed by Jonathan McMaster; Josephine M. Tunney; C. David Garner


Publisher
John Wiley and Sons
Year
2004
Weight
51 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The active sites of molybdenum- and tung
✍ J McMaster; John H Enemark πŸ“‚ Article πŸ“… 1998 πŸ› Elsevier Science 🌐 English βš– 610 KB

Protein X-ray crystallography has revealed the structures of the active sites of several molybdenum- and tungsten-containing enzymes that catalyze formal hydroxylation and oxygen atom transfer reactions. Each molybdenum (or tungsten) atom is coordinated by one (or two) ene-dithiolate groups of a nov