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Chelotropic reactions: The thermal destruction of diazirine

✍ Scribed by James P. Snyder; Russell J. Boyd; M.A. Whitehead

Publisher
Elsevier Science
Year
1972
Tongue
French
Weight
199 KB
Volume
13
Category
Article
ISSN
0040-4039

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✦ Synopsis

Per-n

Prers.

πŸ“œ SIMILAR VOLUMES

On the mechanism of the diazirine exchan
On the mechanism of the diazirine exchange reaction with azide anion
✍ Kathleen E. Bainbridge; William P. Dailey πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 235 KB

Treatment of isotopically labeled bromophenyldiazirine containing one 15N atom with azide ion produces benzonitrile which contains 50% 15N. This suggests that N-azidodiazirines are intermediates in the reaction. Ab initio calculations predict that N-azidodiazirines will have a very low barrier to de