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Chelation-Controlled Intermolecular Hydroacylation: Direct Addition of Alkyl Aldehydes to Functionalized Alkenes.

โœ Scribed by Michael C. Willis; Steven J. McNally; Paul J. Beswick

Publisher
John Wiley and Sons
Year
2004
Weight
141 KB
Volume
35
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Chelation-Assisted
ChemInform Abstract: Chelation-Assisted Intermolecular Hydroacylation: Direct Synthesis of Ketone from Aldehyde and 1-Alkene.
โœ C.-H. JUN; H. LEE; J.-B. HONG ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The work describes a general direct intermolecular hydroacylation -not reported so far -of 1-alkene with aldehyde using the cocatalyst system of the transition metal complex and 2-amino-3-picoline. Some other metal complexes are also catalytically active. Without the addition of the picoline derivat