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Chelating diamide complexes of titanium: new catalyst precursors for the highly active and living polymerization of α-olefins

✍ Scribed by John D. Scollard; David H. McConville; Jagadese J. Vittal; Nicholas C. Payne


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
245 KB
Volume
128
Category
Article
ISSN
1381-1169

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Syntheses of some new group 4 non-Cp com
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## Abstract Totally sixteen new titanium and zirconium non‐Cp complexes supported by Schiff‐base, or thiophene diamide ligands have been synthesized. The complexes are obtained by the reaction of M(OP~T~‐__i__)~4~ (M=Ti, Zr) with the corresponding Schiff‐base ligand in 1: 1 molar ratio in good yiel