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Chelate control in the nickel-complex catalysed homogeneous oligomerization of ethylene

โœ Scribed by Wilhelm Keim; Rolf P. Schulz


Publisher
Elsevier Science
Year
1994
Weight
729 KB
Volume
92
Category
Article
ISSN
0304-5102

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Large-ring P/O chelate nickel complex ca
โœ He-Kuan Luo; Da-Gang Li ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 55 KB

1,1-(Bicyclononyl-9-phosphino)hendecanoic acid and potassium 1,1-(biscyclohexylphosphino) hendecylate were synthesized. A model nickel complex [h 3 ร€C 8 H 13 ]Ni[(C 8 H 14 )P(CH 2 ) 10 COO] containing a 14-membered chelate ring was also synthesized. The catalytic activity of this large chelate ring