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Chelate binding preferences in CpML4 complexes: preparation and structure of trans-(.eta.5-C5H5)Mo[(C6F5)2PCH2CH2P(C6F5)2](CO)Cl

✍ Scribed by Ernst, Michael F.; Roddick, Dean M.

Book ID: 127150127
Publisher: American Chemical Society
Year: 1990
Tongue: English
Weight: 499 KB
Volume: 29
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic00343a067

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## Abstract The cobaltocenium salts [Co{C~5~H~4~(B__i__Pr~2~)}~2~]PF~6~ [(1a)PF~6~] and [Co{C~5~H~4~(BMe~2~)}~2~]PF~6~ [(1b)PF~6~] are strong Lewis acids. With pyridine (1a)PF~6~ forms a mono‐adduct 2 and a di‐adduct 3 which show NMR spectra in the low‐temperature regime of pyridine exchange. With