Charge-transfer rates in symmetric and symmetry-disturbed derivatives of 9,9'-bianthryl
✍ Scribed by Mataga, N.; Yao, H.; Okada, T.; Rettig, W.
- Book ID
- 125535778
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 462 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0022-3654
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Femtosecond-picosecond time-resolved absorption spectral measurements on 9,9'-bianthryl in polar alkanenitrile solvents revealed that the rise curve of the charge-transfer (CT) state contained components with rise times considerably longer than the solvent 7L, which indicated the importance of the t
## Abstract A charge‐transfer (CT) complex composed of racemic __rac__‐10,10′‐dihydroxy‐9,9′‐biphenanthryl as the electron‐donor and the diquaternary derivative of 4,4′‐bipyridinium (viologen) as the electron‐acceptor has been formed by the inclusion of guest molecules. The color and diffuse reflec