The degree of circular polarization gin electronic transitions of chiral molecules is a measure of the ratio of the magnetic and electric dipole transition moments. From theory an upper bound for lgl as a function of dipole strength D can be found. This offers the possibility to distinguish %x\* fro
Charge transfer quenching of 3n,π* and 3π,π* states by O2 in the vapor phase
✍ Scribed by L.S. Bumgarner; F.A. Cebul; K.A. Kirk; D.W. Lupo; L.M. Pittenger; MerlynD. Schuh; M.P. Thomas; I.R. Williams; G.C. Winston
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 71 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0047-2670
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In~mol~~ 2pn\* + 3dn charge transfer in the excited state of phenyl~e occurs very rapidly (<IO ps) both in ?&Fat 293 K and in EPA glass at 77 K. At room temperature a Iong;lived 425 nm transient (which is assgned to a reananged intermediate) is produced with a nse time of 30 ps, showing that the tra
Calculations using the coupled-cluster method with singles and doubles Ž . based on a restricted open Hartree-Fock reference ROHF-CCSD with the augЈ-cc-pVDZ basis set have been carried out to investigate the structures, energies, and vibrational spectra of protonated H CO and of the hydrogen-bonded