In contrast to the UV-photoinduced ligand photoionization of the flavonoid complexes of Fe III , redox reactions initiated in ligand-to-metal charge-transfer excited states were observed on irradiation of the quercetin (1) and rutin (2) complexes of Cu II . Solutions of complexes with stoichiometrie
β¦ LIBER β¦
Charge-transfer photochemistry of copper(II) dithiocarbamate mixed-ligand complexes
β Scribed by B.G. Jeliazkova; M.A. Doicheva
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 404 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0277-5387
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Edge shifts (1E ), effective nuclear charge (Z eff ) and % covalency for some copper(II) mixed-ligand complexes were determined by investigating the copper K-absorption edge using a Seifert x-ray generator and a 0.4 m Cauchois-type bent crystal transmission spectrograph. The shift values are suggest