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Charge-transfer interactions of iodine with some bipyridine isomers

✍ Scribed by Abdulrahman O. Alyoubi

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
50 KB
Volume
48
Category
Article
ISSN
1386-1425

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Using a series o f N-methylated thiohydantoins as substrates, the donor properties o f the sulfur atom are measured by determining the stability constants ( K ) of their adducts with molecular iodine. The K's have been determined by recording the UV-visible spectra of several CH2C12 solutions with d

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The interaction of pyrazolones as a donor with iodine as an acceptor has been studied using spectrophotometric and constant activity methods. The results indicate the formation of 1:1 molecular complex species of n-s\* type. The equilibrium constants of these complexes were determined at different t