Charge-transfer interactions of excited molecules with inorganic anions: the role of spin-orbit coupling in controlling net electron transfer
✍ Scribed by A. Treinin; I. Loeff; J.K. Hurley; H. Linschitz
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 583 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Radical yields in simple anion-organic triplet charge-transfer interactions are interpreted in terms of spin-orbit coupliig in an incipient product radical, as evidenced by increasing yield with increasing I,?F] in cases where k> radicals with zero orbital momentum are formed_ Nitrite may also quench by energy rrzmsfer. The interactions of electronically excited molecules with inorganic anions in polar solvents have been studied extensively [l--4], with special interest being focused recently on the possibility of using such systems as redox couples for solar energy storage, e.g. the anthraquinone-Cl-