Charge-Transfer Interaction of Aromatic Thiols with 2,3-Dichloro-5,6-dicyano- p -benzoquinone: Spectral and Quantum Mechanical Studies
β Scribed by Kalimuthu, Palanisamy; Sivanesan, A.; John, S. Abraham
- Book ID
- 120332416
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 160 KB
- Volume
- 111
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Charge-transfer interactions of octaethylporphycenatozinc(II), ( OEPc ) Zn with 2,6-dichloro-3,5-dicyano-1,4-benzoquinone, DDQ, in non-aqueous solvents are reported. Both optical absorption and cyclic voltammetry studies reveal the formation of stable charge-transfer complexes between ( OEPc ) Zn an
The formation of I: I electron donor-acceptor complexes of 2, 3-dlchloro-5, &dicyano-phenzoquinone with am-aromatics has been studied by conductometric technique. The stoichiometries, the conductance uPand the molar conductancecoefkirnt oM of the complex solutions are reported. The effect of solvent