Polarized Raman and infrared spectra of bis(thiourea)cadmium chloride, a novel semiorganic nonlinear optical crystal, were recorded to determine the symmetries of molecular vibrations. The observed Raman and infrared bands are assigned to molecular vibrations of thiourea, cadmium-sulphur and cadmium
✦ LIBER ✦
Charge transfer interaction and nonlinear optical properties of barium chloride and thiourea complexes: a vibrational spectroscopic study
✍ Scribed by M. Meena Kumari; Miss Pillai Indu Ramachandra; C. Ravikumar; I. Hubert Joe; I. Němec
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 332 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0377-0486
- DOI
- 10.1002/jrs.2854
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## Abstract The second‐order polarizabilities, transition moments, and density of states of aryldiazenido hexamolybdates derivatives were investigated by density functional theory (DFT). System 2 [Mo~6~O~18~(N~2~C~6~H~5~)]^3–^ has a considerably large second‐order polarizability, 14.50 × 10^–30^ es