Charge transfer intensities of iodine complexes with N-heterocyclics
β Scribed by Krishna, V. G.; Bhowmik, Benoy B.
- Book ID
- 118127043
- Publisher
- American Chemical Society
- Year
- 1968
- Tongue
- English
- Weight
- 706 KB
- Volume
- 90
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The interaction of pyrazolones as a donor with iodine as an acceptor has been studied using spectrophotometric and constant activity methods. The results indicate the formation of 1:1 molecular complex species of n-s\* type. The equilibrium constants of these complexes were determined at different t
Using a series o f N-methylated thiohydantoins as substrates, the donor properties o f the sulfur atom are measured by determining the stability constants ( K ) of their adducts with molecular iodine. The K's have been determined by recording the UV-visible spectra of several CH2C12 solutions with d