Charge-transfer-induced change of 181Ta Mössbauer isomer shift in 2H-TaS1 intercalated with hydrated sodium

Direct observation of charge transfer in

Direct observation of charge transfer in lithium-intercalated 2H-Tase2 by 181Ta Mössbauer spectroscopy

✍ M. Eibschutz; D. Salomon; D.W. Murphy; S. Zahurak; J.V. Waszczak 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 231 KB

High resolution Miissbauer resonance of the 6.2 keV y-rays of '\*'Ta have been observed in a single crystal of 2H-TaSez and a lithiated crystal. The lithiated sample has been pepared by a novel technique. The isomer shift (IS) increases from 82.68 mm/s for ZH-TaSez to 107 mm/s for 2H-LiO g,TaSez. Th