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Charge-transfer excited state in tris(acetylacetonato) europium(III)

✍ Scribed by G.D.R. Napier; J.D. Neilson; T.M. Shepherd

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
337 KB
Volume
31
Category
Article
ISSN
0009-2614

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✦ Synopsis

The &emely low effjciency of the intramolecti ener,v trakfer process in europium acetyhcetonate compared With the corresponding terbium acetylacetonate is attriiuted to the presence of a charge-transfer excited state lying below the 'I l&&l singlet states. This is supported by Ihe anomalous absorption speclrum of the Eu3' complex and the effects of added ani,ons in other ligand systems.

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