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Charge-Transfer Complexes of 4-phenyl-1,2,3,5-dithiadiazolyl and 4-Phenyl-1,2,3,5-diselenadiazolyl with Iodine. Preparation and Solid-State Characterization of [PhCN2E2]3[I3] (E = S, Se) and [PhCN2S2][I3]

✍ Scribed by Bryan, C. D.; Cordes, A. W.; Haddon, R. C.; Hicks, R. G.; Oakley, R. T.; Palstra, T. T. M.; Perel, A. S.; Scott, S. R.


Book ID
126799097
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
913 KB
Volume
6
Category
Article
ISSN
0897-4756

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ESR spectra of 4-phenyl-1,2,3,5-diselena
✍ Jeremy M. Rawson; Arthur J. Banister; Iain May πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 422 KB

## Abstract Anisotropic ESR spectra (THF, frozen glass, 77 K) of PhCN~2~Se~2~^Λ™^ provide valuable information about the electronic structure of the diselenadiazolyl radical. Reaction of PhCN~2~Se~2~^Λ™^ with Pt(PPh~3~)~3~ in CH~2~Cl~2~ yielded the first diselenadiazolyl–metal complex, Pt[PhCN~2~Se~2