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Charge transfer and valence isomerization in the decay of electronically excited hexafluorobenzene

✍ Scribed by Joseph L.G. Suijker; Cyril A.G.O. Varma

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
746 KB
Volume
97
Category
Article
ISSN
0009-2614

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✦ Synopsis

Peculiar phorophysical behaviour of hekafluorobenzene (C6F6) in solution has been observed. Laser pulse c.citation at 265 nm generates transient absorptions due fo species X and Y. Species X are identifsd with an inrermediite in the isomerization to the Dewar form. Y seems to be a seminate pair of C& and ChF,, formed only within clusters of CeF, mol-

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