✦ LIBER ✦

Charge-stripping mass spectrometry of molecular ions from polyacenes and molecular orbital theory

✍ Scribed by D. Stahl; F. Maquin

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 342 KB
Volume: 108
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85066-6

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✦ Synopsis

Mc;lsuremcnts of the rransl;itional energy loss accompanying the charge-stripping reactions 31*-k N -M'+ + h' + e have been performed for five molecular ions in the poiytcene series The energy necessary to remow the second electron from an ion, &in = IE(hI+* 31 3), is found t o correlate with the energy level of the highest occupied molecular orbital. The esperimentnl findings are discussed in terms of Hiickei molecular-orbital theory.

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