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Charge Penetration and the Origin of Large O−H Vibrational Red-Shifts in Hydrated-Electron Clusters, (H 2 O) n -

✍ Scribed by Herbert, John M.; Head-Gordon, Martin


Book ID
126120457
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
258 KB
Volume
128
Category
Article
ISSN
0002-7863

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Size-dependent collisional incorporation
✍ Paul J. Campagnola; Donna M. Cyr; Mark A. Johnson 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 632 KB

We report a rapid increase in the propensity of D,O molecules to incorporate into (H,O); clusters upon collisions between D,O and a distribution of (H\*O);, 6< n c 25, clusters. We interpret this effect by invoking a size-dependent associative electron detachment cross section which increases rapidl