Charge ordered state in (BEDT-TTF)3Cl2·2H2O
✍ Scribed by T. Ogura; A. Kawamoto; K. Kumagai; H. Taniguchi
- Book ID
- 110621219
- Publisher
- Springer US
- Year
- 2006
- Tongue
- English
- Weight
- 212 KB
- Volume
- 142
- Category
- Article
- ISSN
- 0022-2291
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The X-ray crystal structure of (BEDT-TTF) 3 Cl 2 ' (H 2 O) 2 [BEDT-TTF ؍ bis(ethylenedithio)tetrathiafulvalene] has been determined at 190, 130, and 10 K. The broad metal+insulator transition (100+160 K) observed in the resistivity data at ambient pressure, and the pressure induced superconductivi
Two new charge transfer salts of BEDT-TTF, bis (ethylenedithio) tetrathiafulvalene, with thiocyanato-metal complex anions have been synthesized and characterized as (BEDT-TTF) 4 [Fe(NCS) 6 ] ' CH 2 Cl 2 and (BEDT-TTF) 2 [Cr(NCS) 4 (bipym)] ' 0.15H 2 O, where bipym ؍ 2,2-bipyrimidine. The Fe salt,