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Charge densities, bond orders and delocalization energies of the pentalene dianion and the heptalene dication

✍ Scribed by A.J. Silvestri; L. Goodman; J.A. Dixon


Book ID
103391366
Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
522 KB
Volume
18
Category
Article
ISSN
0040-4020

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Y vs. cyclic delocalization in small rin
✍ Timothy Clark; Dieter Wilhelm; Paul von RaguΓ© Schleyer πŸ“‚ Article πŸ“… 1982 πŸ› Elsevier Science 🌐 French βš– 194 KB

Coulombic repulsion in four membered ring dications and dianions is more important than HUckel aromaticity and leads to a preference for Y-delocalized isomers with more favorable n charge distributions. The most significant advances in the history of organic chemistry include the concept of cyclic a