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Charcoal-catalyzed transfer of tritium into 3H2O from regiospecifically-labeled 2-hydroxyestradiol in the presence of thiols

โœ Scribed by Peter H. Jellinck; Jack Fishman


Book ID
119481564
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
356 KB
Volume
43
Category
Article
ISSN
0039-128X

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The catalytic system PdCI,(PPh,),-HCI is highly active and selective in the hydrogen transfer reaction from H,O-CO to PhCOCH,CHOHCOOH which yields the corresponding y-keto acid PhCOCH,CH,COOH, with concomitant evolution of C02. An increase of temperature, pressure of carbon monoxide and catalyst con