derived from BaCO 3 . Small particle size has been shown to suppress a martensitic phase transition, and in this context microwave plasma synthesis appears rapid enough to prevent particle sintering and subsequent transition to the monoclinic phase. Prolonged exposure (1 h) to an O 2 or Ar plasma of
Characterization of ZnO nanorods grown on Si substrates coated with NiCl2
β Scribed by Jie Wang; Huizhao Zhuang; Junlin Li; Peng Xu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 154 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0232-1300
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
ZnO nanorods were synthesized on NiCl~2~βcoated Si substrates via a chemical vapor deposition (CVD) process. The asβfabricated nanorods with diameters ranging from 150 nm to 200 nm and lengths up to several tens of micrometers grew preferentially arranged along [0001] direction, perpendicular to the (0002) plane. The clear lattice fringes in HRTEM image demonstrated the growth of good quality hexagonal singleβcrystalline ZnO. Room temperature photoluminescence (PL) spectra illustrated that the ZnO nanorods exhibit strong UV emission peak and green emission peak, peak centers located at 388 nm and 506 nm. A possible growth mechanism based on the study of our Xβray diffraction (XRD), electron microscopy and PL spectroscopy was proposed, emphasizing the effect of NiCl~2~ solution (Β© 2010 WILEYβVCH Verlag GmbH & Co. KGaA, Weinheim)
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