Characterization of the krypton dichloride and xenon dichloride van der Waals isomers
β Scribed by Bieler, Craig R.; Spence, Kevin E.; Janda, Kenneth C.
- Book ID
- 121696863
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 860 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
From the free jet millimeter-wave spectra of four isotopomers of the weakly bonded oxiraneβ’ β’ β’Kr complex, information on the equilibrium conformation, dynamics, and dissociation energy has been deduced. A C s symmetry is found for the complex, with Kr lying in the Ο v plane of symmetry of oxirane.
Spectroscopic constants and potential curves for the X 'I&,& and C 'n, states of ZnAr were determined by laser-induced fluorescence of ZnAr van der Waals molecules prepared and cooled in a supersonic jet of oven-generated zinc vapor and argon gas.