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Characterization of synthetic oxomanganese complexes and the inorganic core of the O2-evolving complex in photosystem II: Evaluation of the DFT/B3LYP level of theory

โœ Scribed by Eduardo M. Sproviero; Jose A. Gascon; James P. McEvoy; Gary W. Brudvig; Victor S. Batista


Book ID
108174933
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
500 KB
Volume
100
Category
Article
ISSN
0162-0134

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Inorganic cofactors (Mn, Ca(2+) and Cl(-)) are essential for oxidation of H2O to O2 by Photosystem II. The Mn reductants NH2OH and its N-methyl derivatives have been employed as probes to further examine the interactions between these species and Mn at the active site of H2O oxidation. Results of th