Characterization of some derivatives of ferrocene and (η6-benzene)tricarbonylchromium(0) by micro-Raman spectroscopy

First Synthesis and Structural Character

First Synthesis and Structural Characterization of Neutral Chelated syn-Facial Bimetallic (η5-Cyclohexadienyl)benzylidene Complexes from Tetracarbonyl[2-{(η6-phenyl)tricarbonylchromium(0)-ĸC2′}pyridine-ĸN]manganese(I) Derivatives

✍ Jean-Pierre Djukic; Aline Maisse; Michel Pfeffer; Karl Heinz Dötz; Martin Nieger 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 371 KB 👁 2 views

Reaction of tetracarbonyl[2-{(η 6 -phenyl)tricarbonylchro-quinoline, 2b and 2c, with PhLi and subsequently with MeOSO 2 CF 3 affords deep purple crystalline products 4b and mium-κC 2Ј }pyridine-κN]manganese(I), 2a, with phenyllithium quantitatively affords an acylmanganese anion 3a 4c that have been