The cobalt-60 radiation-induced graft copolymerization of 2-hydroxyethyl methacrylate (HEMA) onto a chloroprene rubber (CR) membrane has been studied in ethanol. The structure, morphology, crystallinity, thermal stability, and hydrophility of graft copolymer were characterized by means of Fourier tr
Characterization of plasma-induced graft polymerization of 2-hydroxyethyl methacrylate onto silicone rubber
โ Scribed by Shyh-Dar Lee; Ging-Ho Hsiue; Chee-Chan Wang
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 793 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
Graft copolymerization of 2-hydroxyethyl methacrylate ( HEMA) as attempted onto the surface of silicone rubber membrane, which was pretreated by Ar-plasma, then exposed in oxygen to introduce a peroxide group. The effect of the amount of HEMA grafted on Arplasma-treated and graft copolymerization was examined for various parameters of power, pressure, time, reaction time, and concentration of HEMA aqueous solution. The surfaces were characterized by ATR-FTIR, ESCA, contact angle, and SEM. PHEMA was indicated by ATR-FTIR and ESCA analysis to be present successfully onto the grafted surface of silicone rubber membrane. The stable wettability, as demonstrated once the PHEMA grafted films, indicated contact with a hydrated environment by the study of contact angle.
๐ SIMILAR VOLUMES
Grafting of 2-hydroxyethyl methacrylate(HEMA) onto chloroprene rubber(CR) membrane was carried out in ethanol by direct cobalt-60 gamma ray irradiation. The kinetics of the grafting reaction was studied in respect of concentration of monomer, dose rate and temperature. The experimental results show
Two-hydroxyethyl methacrylate was grafted onto cotton cellulose using photoinitiation technique in the presence of the photoinitiator benzoin ethyl ether. Various parameters of the graft-copolymerization reaction, namely time, temperature, initiator, and monomer concentrations, were optimized using